By measurement principle

Optical Concentration Meter

inline refractometer · refractive index meter · spectroscopic concentration meter · online refractometer

Light passing a liquid is refracted and absorbed. Refractive index tracks total dissolved solids; absorption at characteristic wavelengths tracks specific components. One answers "how much", the other "which".

2Models
Optical concentration measurement: the total-reflection critical angle on a sapphire prism, and multi-wavelength absorption spectroscopy

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Two optical routes that have almost nothing in common

Refractive index — how much is dissolved

Light crosses a sapphire prism towards the liquid and undergoes total internal reflection beyond the critical angle. The position of the resulting shadow line is set by the refractive index of the liquid, and a CCD reads that position. Refractive index against total dissolved concentration is a stable single-valued curve, so this instrument answers "how much is dissolved" — Brix, brine strength, acid concentration, glycol content, coolant ratio. PS7110 takes this route.

Its strength is often misunderstood: the measurement happens within a few micrometres of the prism face, so it is indifferent to suspended solids, bubbles and colour. Dark, opaque liquid measures perfectly well, because the light was never going to cross it. Its weakness is equally sharp: the prism has to stay clean. Once a film, an oil layer or crystal forms, the critical angle is set by that layer and not by the process.

Spectroscopy — which component

Different molecules absorb characteristically across the UV, visible and near-infrared. Measuring absorbance at several wavelengths and fitting a calibration model separates components — free chlorine and free alkali reported at the same time, or two acids distinguished in a mixture. PS7100 takes this route.

What a spectroscopic analyser can do is set by its calibration: it is accurate over the conditions the model has seen and extrapolates badly beyond them. Commissioning takes longer than for any other principle here, and the payoff is a multi-component answer nothing else on this page can give.

Against the other principles

A refractometer and a fork or Coriolis are not measuring the same thing: those measure density, this measures refractive index. In a binary solution the two are interchangeable; add a third variable — temperature, suspended solids, a second solute — and they diverge, and which one is "right" depends on what you are controlling.

Against ultrasonic sound velocity: both target clean liquid. Sound velocity does not care about a dirty window but does care about bubbles; refractive index does not care about bubbles or particles but does care about films. Dirty and gas-free points to optical; gassy and clean points to ultrasound.

The window is the whole story

Every optical concentration meter is accurate on the bench. On site, the difference between them is almost entirely whether the window stays clean. Three rules that hold up:

  • Mount where the liquid moves and cleans the face. A probe in a dead zone fouls within a week.
  • For film-forming media, fit steam or liquid purge and put the purge interval into the control logic rather than into someone's memory.
  • Treat zero drift as a fouling alarm, not an instrument fault. A periodic water zero check is the single most effective maintenance routine for this class of meter.

Buying from China

CE marked; ATEX / IECEx varies by configuration and hygienic (3-A / EHEDG) options exist for food and beverage duty — confirm both against your specification before ordering. Quotations in USD or EUR on EXW, FOB Shanghai or CIF, with HS code and declaration of conformity. For a spectroscopic application, send the medium composition and its expected range with the enquiry: the calibration plan, not the hardware, decides whether the project succeeds.

Where it works

  • Dissolved concentration: Brix, brine, acid and caustic strength, glycol and coolant ratio
  • Dark or turbid liquids that do not form films — a refractometer needs no transparency
  • Multi-component systems where the components must be reported separately (spectroscopic)
  • Crystallisation control and evaporation end-point
  • Food and beverage, fine chemicals, electronic chemicals, battery electrolyte

Where it doesn't

  • Film-forming, oily or crystallising media with no purge available
  • High-solids mineral slurry — not impossible, but the window maintenance does not pay
  • Duties that need bulk density rather than dissolved concentration (use a fork, ultrasound or Coriolis)
  • Complex mixtures with no way to collect enough calibration samples (spectroscopic)

Common questions

Does the PS7110 prism need cleaning, and how often should it be checked?
A clean prism face is the single precondition for a trustworthy reading. Coating, scale, crystals or abrasion change the reading directly, and the instrument does NOT raise a fault when they do — it shows up as a slow one-way drift on an unusually smooth curve. So the cleaning strategy belongs in the design, not in a response to a reading that has already drifted. The prism material depends on the variant: high-strength optical glass on the A, sapphire on the B and C. For media that coat or crystallise, the PS7110-CL1 ultrasonic cleaning unit keeps the face clean continuously and the PS7110-CL2 high-pressure flushing unit flushes it periodically; sanitary processes can use CIP and SIP directly, with a cleaning temperature range of −30 to 120 °C. Where the medium can carry grit or abrasive particles, filter them out upstream or the detection window will be worn away. Putting "look at the face" into the routine inspection is worth more than any coefficient correction applied afterwards; the sensor status diagnostics help, but they do not replace looking.
Can PS7100 spectroscopy measure multiple components simultaneously?

Yes. The PS7100 employs a full-spectrum UV-Vis-NIR absorption method (200–1,700 nm) combined with an MLR multivariate linear regression algorithm, enabling the simultaneous output of concentrations for multiple components in a single measurement.

Typical applications:

  1. In chlor-alkali sodium hypochlorite production, it simultaneously measures effective chlorine and free alkali NaOH (model R² > 0.99);
  2. Dual-component analysis of mixed acid solutions (HCl + H₂SO₄);
  3. Semiconductor wet etching solutions (HF + HNO₃);
  4. Simultaneous monitoring of sugar content and alcohol content in pharmaceutical fermentation broths.

The multi-component capability requires preliminary modeling; Pisonics will develop a dedicated MLR model in its headquarters laboratory based on the customer’s media samples, with a modeling cycle of 2–4 weeks.

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